ி
ௌ
mising the posterior with respect to ߪி
ଶ leads to the calculation of
n below,
ߪி
ଶൌ܍௧Γ܍2ߚி
2ߙி2 ܭ
(5.27)
mising the posterior with respect to ߪௌ
ଶ leads to the calculation of
n below,
ߪௌ
ଶൌ
܌௧܌2ߚௌ
2ߙௌ2 ܰെ1
(5.28)
the posterior is maximised with respect to the baseline b, the
g equation is derived, which is similar to WH,
܊ൌߪி
ିଶ܈ିଵΓܛ
(5.29)
alled the mapping construction matrix and is defined as below,
ۉ
ۇ
ߪி
ିଶݐଵߪௌ
ିଶ
െߪௌ
ିଶ
െߪௌ
ିଶ
ߪி
ିଶݐଶߪௌ
ିଶ
⋯
0
0
⋮
⋱
⋮
0
0
⋯
ߪி
ିଶݐேߪௌ
ିଶ
ۊ
(5.30)
ی
e 5.11 shows the estimated baseline using BWH for the spectra
Figure 5.5. In Figure 5.11, the grey line is the raw spectrum and
ine is the estimated baseline. An obvious benefit of BWH is that
spectrum generated by BWH will have small degrees of artifacts
d with those shown in Figures 5.7–5.9. The consequence is that
peak recognition will be more efficient.